XII CBSE CHEMISTRY(043)-2016 MODEL SET-1


DR SUDHIR TOMAR
MODEL CBSE BOARD PAPER XII CHEMISTRY-(043)
2015-2016 SET -1


Dr. Sudhir Tomar
1/1/2016




                  SAMPLE QUESTION PAPER
                           CHEMISTRY (043)
                        CLASS- XII - (2015-16)

: Time Allowed: 3 Hrs                                                          Maximum Marks 70

General Instructions:

1. All questions are compulsory.

2. Question No. 1-5 are very short answer questions and carry 1 mark each.

3. Question No. 6-10 is short answer questions and carries 2 marks each.

4. Question No. 11-22 is also short answer questions and carries 3 marks each.

5. Question No. 23 is value added questions and carry 4 marks.

6. Question No. 24-26 carry 5 marks

7. Use log tables if necessary, use of calculators is not allowed.













Q1.  What is co-ordination number when an atom occupying the position in deep of first row in two  
  Dimensional.
Q2.  What happen when R.B.C is putted in 0.75% aqueous solution of NaCl?
Q3.  What is peptisation?
Q4.  What happens when glucose reacts with red P and HI. Give equation?
Q5.  Write IUPAC name of C 6H 5-CH 2-CH 2NH 2.
Q6.  Write short notes on
(i)                  Alpha helix and beta pleated sheet.
(ii)                Denaturation of proteins.
OR
          Write difference between DNA &RNA
Q7.  How you will distinguish between.
(i)                  Formaldehyde and acetaldehyde.
(ii)                Methyl alcohol and ethyl alcohol.
Q8.  Write notes on.
                (i)Garbriel pthalamide reaction.
                (ii) Etard reaction
Q9.  Convert the following.
(i)                  Phenol into aspirin
(ii)                Methane amine into ethane amine

Q10.  Arrhenius reaction follows the first order kinetics. This is
                                                K= A.e-28000K/T      .Find out activation energy.
Q11.   (i)Elements having mass 56 occupying FCC geometry. If edge length is 200 pm then
            Find out density of this crystal?
            (ii)Why NaCl Impart yellow colour, when it keep in contact with air?
   Q12.  (i) 5% aqueous solution of glucose is isotonic with 0.897% aqueous solution of cane
            Sugar. Find out molecular mass of sugar.
            (ii) 0.45 M solution of Cacl2 undergoes 40% dissociation find out elevation in boiling
            point.Kb =1.35 k kg/ mol.
Q13.   (i) If a Radioactive substance undergoes 50% dissociation in 10 min.How much amount of
            it will left in 25 min?
            (ii)Define rate of reaction.
Q14.   (i) A cell is given
            Ag/Ag +(0.2M )   //   Ni 2+ ( 0.1M)/Ni
             If E0 Cell  =1.26 V. Find out overall potential of this cell?
            (ii)How much faraday will be required to deposit 27 gm of Al from molten Alcl3?
Q15.      (i) What do you mean by acidic flux.
            (ii)What is the role of pine oil in froath flotation process?
            (iii)Which type of metal can be purified by zone refining?
Q16.    (i)Write IUPAC name of     K2 [Zn (en)3(HO)2]
            (ii)Complex [Ni (CO)4] occupying colourless while [Nicl4]2- is coloured. Show how it is
            Possible.
Q17.    Give chemical equation which occur
(a) duing the test of drunker driver?
            (b) White phosphorous react with water in alkali medium?
            (c)XeF 6    +   H 2O   ---------------à
Q18.    (i)Drow the structure of    (a) HclO4                           (b)   H 2S2  O 8
(iii)             Icl3 is more reactive then I2.?
Q19     (i) Give the chemical equation for the preparation of  KMnO4?
         (ii)Mn3+ and Cr2+   both have d4 configuration but Mn3+ act as
            Oxidizing while Cr2+acts as reducing agent. Explain?
Q20.(i) Phenol show acidic character but other alcohol does not.Expalin?
            (ii)Aniline does not give friedal craft reaction?
            (iii)An organic compound has C 5H 10formula. It does not react with cl 2 in dark but give
            Monohalogen derivatives in sun light. What is the IUPAC name of organic compound?
Q21.    (i) What is difference between between Buna-N AND Buna-S.?
            (ii)What do you mean by vulcanization?
            (iii)Write monomers and uses of nylon-6?
Q22.     (I)What do you mean by Broad spectrum antibiotics?
            (ii)What are antihistamines? Give examples?
            (iii)What is role of tranquilizers in sleeping pills?
Q23.Harimohan is diabetic patient. Now days he is suffering from infection and fever. His neighbor tells him to take aspirin twice a day so that his fever and pain will control. Harimohan follow the direction of his neighbor because he was an old man and educated person, but Harimohan problem raise in two three days …
Read the above passage and answer the following question
            (i)Is it safe aspirin for Harimohan?
            (ii)What should Harimohan do?
            (iii)Why Harimohan suffering from fever?
            (iv)What precaution Harimohan should follow?
Q24     (i) What is the coordination number of carbon, in diamond?
            (ii)What kind of adsorption is represented by the following graph?

(iii)Arrange the following in Acidic strength:
HNO3, H3PO4, H3AsO4
(iv)         HClO4 is more acidic than HClO3.
(v)          Sc3+ is more stable than Sc2+.

Q25.    (i)What is the equivalent wt. of KMnO4 in?
(a)  Acidic Medium (b) Neutral Medium (c) In alkaline Medium

(iii)          How t2g and eg orbitals are formed in an octahedral complex?
Q26.    (i)A cationic complex has two isomers A & B. Each has one Co3+, five NH3, one Br and one SO42. A gives a white precipitate with BaCl2 solution while B gives a yellow precipitate with AgNO3 solution.
            (a)        What are the possible structures of the complexes A and B ?
            (a)        Will the two complexes have same colour?

            (ii)Identify A, B, C, D, E, R, R¹ in the following:
Graphic1
 
                                                     Dry ether       H2O
            (i)                     Br + Mg ————® A ————® B

                                             Dry ether                  D2O
            (ii)        R — Br + Mg ————® C ————® CH3 — CH — CH3
                                                                                                               |
                                                                                                               D
                                 CH3 CH3
                                   |             |                Na/ether                   Mg             H2O
            (iii)       CH3 — C — C — CH3 ¬———— R¹X ———® D ———® E
                                   |             |
                                 CH3 CH3
           
******************************************************************************************************
                                
DR SUDHIR TOMAR
                                                M.Sc (inorganic chemistry).M.Sc (physical chemistry)
                                                M.Ed,,ph.D,,LLB
                                                Email;;drsudhirtomar@gmail.com
                                                Bloog;;drsudhirkumarchemistry.blogspot.com
                                                Cont;;9718704142

BY -DR SUDHIR TOMAR



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